Abstract
The single-crystal to single-crystal (SCSC) conversion of metal-organic frameworks (MOFs) represents a facile route to new MOFs with structures and functionalities that are challenging to obtain by direct synthesis. However, conversion products are often structurally limited for a given precursor. We herein report that a two-dimensional (2D) MOF featuring a linear Cd3 cluster secondary building unit (SBU) converts into one type of three-dimensional (3D) interpenetrated and two types of 3D non-interpenetrated MOFs upon reaction with dipyridyl ligands. One of the interpenetrated 3D MOFs, in turn, undergoes either ligand substitution to give isoreticular interpenetrated MOFs, or ligand addition to give a self-penetrated 3D MOF. This rich SCSC conversion library is made possible by the inclined nature of the Cd3 SBU with respect to the 2D plane of the starting material to create an anisotropic environment around the SBU.
| Original language | English |
|---|---|
| Pages (from-to) | 724-729 |
| Number of pages | 6 |
| Journal | Crystal Growth and Design |
| Volume | 19 |
| Issue number | 2 |
| Early online date | 27 Dec 2018 |
| DOIs | |
| Publication status | Published - Feb 2019 |
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A Single-Crystal to Single-Crystal Conversion Scheme for a Two-Dimensional Metal-Organic Framework Bearing Linear Cd3 Secondary Building Units. / Chao, Meng Yao; Chen, Jing; Hao, Zhi Min; Tang, Xiao Yan; Ding, Lifeng; Zhang, Wen Hua; Young, David J.; Lang, Jian Ping.
In: Crystal Growth and Design, Vol. 19, No. 2, 02.2019, p. 724-729.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - A Single-Crystal to Single-Crystal Conversion Scheme for a Two-Dimensional Metal-Organic Framework Bearing Linear Cd3 Secondary Building Units
AU - Chao, Meng Yao
AU - Chen, Jing
AU - Hao, Zhi Min
AU - Tang, Xiao Yan
AU - Ding, Lifeng
AU - Zhang, Wen Hua
AU - Young, David J.
AU - Lang, Jian Ping
PY - 2019/2
Y1 - 2019/2
N2 - The single-crystal to single-crystal (SCSC) conversion of metal-organic frameworks (MOFs) represents a facile route to new MOFs with structures and functionalities that are challenging to obtain by direct synthesis. However, conversion products are often structurally limited for a given precursor. We herein report that a two-dimensional (2D) MOF featuring a linear Cd3 cluster secondary building unit (SBU) converts into one type of three-dimensional (3D) interpenetrated and two types of 3D non-interpenetrated MOFs upon reaction with dipyridyl ligands. One of the interpenetrated 3D MOFs, in turn, undergoes either ligand substitution to give isoreticular interpenetrated MOFs, or ligand addition to give a self-penetrated 3D MOF. This rich SCSC conversion library is made possible by the inclined nature of the Cd3 SBU with respect to the 2D plane of the starting material to create an anisotropic environment around the SBU.
AB - The single-crystal to single-crystal (SCSC) conversion of metal-organic frameworks (MOFs) represents a facile route to new MOFs with structures and functionalities that are challenging to obtain by direct synthesis. However, conversion products are often structurally limited for a given precursor. We herein report that a two-dimensional (2D) MOF featuring a linear Cd3 cluster secondary building unit (SBU) converts into one type of three-dimensional (3D) interpenetrated and two types of 3D non-interpenetrated MOFs upon reaction with dipyridyl ligands. One of the interpenetrated 3D MOFs, in turn, undergoes either ligand substitution to give isoreticular interpenetrated MOFs, or ligand addition to give a self-penetrated 3D MOF. This rich SCSC conversion library is made possible by the inclined nature of the Cd3 SBU with respect to the 2D plane of the starting material to create an anisotropic environment around the SBU.
UR - http://www.scopus.com/inward/record.url?scp=85060027644&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.8b01311
DO - 10.1021/acs.cgd.8b01311
M3 - Article
VL - 19
SP - 724
EP - 729
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 2
ER -