A Single-Crystal to Single-Crystal Conversion Scheme for a Two-Dimensional Metal-Organic Framework Bearing Linear Cd3 Secondary Building Units

Meng Yao Chao, Jing Chen, Zhi Min Hao, Xiao Yan Tang, Lifeng Ding, Wen Hua Zhang, David J. Young, Jian Ping Lang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The single-crystal to single-crystal (SCSC) conversion of metal-organic frameworks (MOFs) represents a facile route to new MOFs with structures and functionalities that are challenging to obtain by direct synthesis. However, conversion products are often structurally limited for a given precursor. We herein report that a two-dimensional (2D) MOF featuring a linear Cd3 cluster secondary building unit (SBU) converts into one type of three-dimensional (3D) interpenetrated and two types of 3D non-interpenetrated MOFs upon reaction with dipyridyl ligands. One of the interpenetrated 3D MOFs, in turn, undergoes either ligand substitution to give isoreticular interpenetrated MOFs, or ligand addition to give a self-penetrated 3D MOF. This rich SCSC conversion library is made possible by the inclined nature of the Cd3 SBU with respect to the 2D plane of the starting material to create an anisotropic environment around the SBU.

Original languageEnglish
Pages (from-to)724-729
Number of pages6
JournalCrystal Growth and Design
Volume19
Issue number2
Early online date27 Dec 2018
DOIs
Publication statusPublished - Feb 2019

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Bearings (structural)
Metals
Single crystals
single crystals
metals
Ligands
ligands
Substitution reactions
routes
substitutes

Cite this

Chao, Meng Yao ; Chen, Jing ; Hao, Zhi Min ; Tang, Xiao Yan ; Ding, Lifeng ; Zhang, Wen Hua ; Young, David J. ; Lang, Jian Ping. / A Single-Crystal to Single-Crystal Conversion Scheme for a Two-Dimensional Metal-Organic Framework Bearing Linear Cd3 Secondary Building Units. In: Crystal Growth and Design. 2019 ; Vol. 19, No. 2. pp. 724-729.
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abstract = "The single-crystal to single-crystal (SCSC) conversion of metal-organic frameworks (MOFs) represents a facile route to new MOFs with structures and functionalities that are challenging to obtain by direct synthesis. However, conversion products are often structurally limited for a given precursor. We herein report that a two-dimensional (2D) MOF featuring a linear Cd3 cluster secondary building unit (SBU) converts into one type of three-dimensional (3D) interpenetrated and two types of 3D non-interpenetrated MOFs upon reaction with dipyridyl ligands. One of the interpenetrated 3D MOFs, in turn, undergoes either ligand substitution to give isoreticular interpenetrated MOFs, or ligand addition to give a self-penetrated 3D MOF. This rich SCSC conversion library is made possible by the inclined nature of the Cd3 SBU with respect to the 2D plane of the starting material to create an anisotropic environment around the SBU.",
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A Single-Crystal to Single-Crystal Conversion Scheme for a Two-Dimensional Metal-Organic Framework Bearing Linear Cd3 Secondary Building Units. / Chao, Meng Yao; Chen, Jing; Hao, Zhi Min; Tang, Xiao Yan; Ding, Lifeng; Zhang, Wen Hua; Young, David J.; Lang, Jian Ping.

In: Crystal Growth and Design, Vol. 19, No. 2, 02.2019, p. 724-729.

Research output: Contribution to journalArticleResearchpeer-review

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