Abstract
The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions
| Original language | English |
|---|---|
| Pages (from-to) | m897-m898 |
| Number of pages | 2 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | E68 |
| Issue number | Part 7 |
| DOIs | |
| Publication status | Published - 1 Jul 2012 |
| Externally published | Yes |
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(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II). / Najib, Muhd Hidayat Bin; Tan, Ai Ling; Young, David J.; Ng, Seik Weng; Tiekink, Edward R T.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. E68, No. Part 7, 01.07.2012, p. m897-m898.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - (Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)
AU - Najib, Muhd Hidayat Bin
AU - Tan, Ai Ling
AU - Young, David J.
AU - Ng, Seik Weng
AU - Tiekink, Edward R T
PY - 2012/7/1
Y1 - 2012/7/1
N2 - The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions
AB - The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions
UR - http://www.scopus.com/inward/record.url?scp=84863589634&partnerID=8YFLogxK
U2 - 10.1107/S1600536812025664
DO - 10.1107/S1600536812025664
M3 - Article
VL - E68
SP - m897-m898
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 1600-5368
IS - Part 7
ER -