(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)

Muhd Hidayat Bin Najib, Ai Ling Tan, David J. Young, Seik Weng Ng, Edward R T Tiekink

Research output: Contribution to journalArticle

2 Downloads (Pure)

Abstract

The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions

Original languageEnglish
Pages (from-to)m897-m898
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE68
Issue numberPart 7
DOIs
Publication statusPublished - 1 Jul 2012
Externally publishedYes

Fingerprint Dive into the research topics of '(Acetato-κO)(acetato-κ<sup>2</sup>O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN<sup>2</sup>)quinoline-κN]zinc(II)'. Together they form a unique fingerprint.

  • Cite this