(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)

Muhd Hidayat Bin Najib, Ai Ling Tan, David J. Young, Seik Weng Ng, Edward R T Tiekink

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Abstract

The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions

Original languageEnglish
Pages (from-to)m897-m898
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE68
Issue numberPart 7
DOIs
Publication statusPublished - 1 Jul 2012
Externally publishedYes

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quinoline
Zinc
zinc
Atoms
Ligands
Chelation
carboxylates
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Najib, Muhd Hidayat Bin ; Tan, Ai Ling ; Young, David J. ; Ng, Seik Weng ; Tiekink, Edward R T. / (Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II). In: Acta Crystallographica Section E: Structure Reports Online. 2012 ; Vol. E68, No. Part 7. pp. m897-m898.
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title = "(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)",
abstract = "The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) {\AA}]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions",
author = "Najib, {Muhd Hidayat Bin} and Tan, {Ai Ling} and Young, {David J.} and Ng, {Seik Weng} and Tiekink, {Edward R T}",
year = "2012",
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day = "1",
doi = "10.1107/S1600536812025664",
language = "English",
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pages = "m897--m898",
journal = "Acta Crystallographica Section E: Crystallographic Communications",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "Part 7",

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(Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II). / Najib, Muhd Hidayat Bin; Tan, Ai Ling; Young, David J.; Ng, Seik Weng; Tiekink, Edward R T.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. E68, No. Part 7, 01.07.2012, p. m897-m898.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - (Acetato-κO)(acetato-κ2O,O′)[2-(3, 5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline-κN]zinc(II)

AU - Najib, Muhd Hidayat Bin

AU - Tan, Ai Ling

AU - Young, David J.

AU - Ng, Seik Weng

AU - Tiekink, Edward R T

PY - 2012/7/1

Y1 - 2012/7/1

N2 - The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions

AB - The ZnII atom in the title compound, [Zn(C2H 3O2)2(C14H13N 3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋅⋅⋅O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H⋅⋅⋅O interactions

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