AnN,N'-diethylformamide solvent-induced conversion cascade within a metal-organic framework single crystal

Jing Chen; Meng Yao Chao; Yan Liu; Bo Wei Xu; Wen Hua Zhang; David J. Young

doi:10.1039/d0cc02420a

AnN,N'-diethylformamide solvent-induced conversion cascade within a metal-organic framework single crystal

Jing Chen, Meng Yao Chao, Yan Liu, Bo Wei Xu, Wen Hua Zhang, David J. Young

CDU College of Engineering, IT and Environment

Research output: Contribution to journal › Article

Abstract

Crystals of a two-dimensional (2D) metal-organic framework (MOF) [Cd₃(BTB)₂(DEF)₄]·2(DEF)_0.5(1; BTB = benzene-1,3,5-tribenzolate; DEF =N,N'-diethylformamide) immersed in a solution oftrans-1,2-bis(4-pyridyl)ethylene (BPEE) yields an interpenetrated three-dimensional (3D) MOF of [Cd₃(BTB)₂(BPEE)(H₂O)₂]·(BPEE)·xSol (2). Crystals of MOF2, in turn, undergo a cascade conversion when immersed in DEF, yielding [Cd₃(BTB)₂(BPEE)_1.8(DEF)_0.9(H₂O)_0.8]·xSol (3a) over 100 seconds and [Cd₃(BTB)₂(BPEE)₂(DEF)₂]·xSol (4) after one hour, before finally shuttling back to MOF 1 after six hours.

Original language	English
Pages (from-to)	5877-5880
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	44
DOIs	https://doi.org/10.1039/d0cc02420a
Publication status	Published - 4 Jun 2020

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@article{d0da1712d0034e1792dabd7e3f022127,

title = "AnN,N'-diethylformamide solvent-induced conversion cascade within a metal-organic framework single crystal",

abstract = "Crystals of a two-dimensional (2D) metal-organic framework (MOF) [Cd3(BTB)2(DEF)4]·2(DEF)0.5(1; BTB = benzene-1,3,5-tribenzolate; DEF =N,N'-diethylformamide) immersed in a solution oftrans-1,2-bis(4-pyridyl)ethylene (BPEE) yields an interpenetrated three-dimensional (3D) MOF of [Cd3(BTB)2(BPEE)(H2O)2]·(BPEE)·xSol (2). Crystals of MOF2, in turn, undergo a cascade conversion when immersed in DEF, yielding [Cd3(BTB)2(BPEE)1.8(DEF)0.9(H2O)0.8]·xSol (3a) over 100 seconds and [Cd3(BTB)2(BPEE)2(DEF)2]·xSol (4) after one hour, before finally shuttling back to MOF 1 after six hours.",

author = "Jing Chen and Chao, {Meng Yao} and Yan Liu and Xu, {Bo Wei} and Zhang, {Wen Hua} and Young, {David J.}",

year = "2020",

month = jun,

day = "4",

doi = "10.1039/d0cc02420a",

language = "English",

volume = "56",

pages = "5877--5880",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry (RSC)",

number = "44",

}

TY - JOUR

T1 - AnN,N'-diethylformamide solvent-induced conversion cascade within a metal-organic framework single crystal

AU - Chen, Jing

AU - Chao, Meng Yao

AU - Liu, Yan

AU - Xu, Bo Wei

AU - Zhang, Wen Hua

AU - Young, David J.

PY - 2020/6/4

Y1 - 2020/6/4

N2 - Crystals of a two-dimensional (2D) metal-organic framework (MOF) [Cd3(BTB)2(DEF)4]·2(DEF)0.5(1; BTB = benzene-1,3,5-tribenzolate; DEF =N,N'-diethylformamide) immersed in a solution oftrans-1,2-bis(4-pyridyl)ethylene (BPEE) yields an interpenetrated three-dimensional (3D) MOF of [Cd3(BTB)2(BPEE)(H2O)2]·(BPEE)·xSol (2). Crystals of MOF2, in turn, undergo a cascade conversion when immersed in DEF, yielding [Cd3(BTB)2(BPEE)1.8(DEF)0.9(H2O)0.8]·xSol (3a) over 100 seconds and [Cd3(BTB)2(BPEE)2(DEF)2]·xSol (4) after one hour, before finally shuttling back to MOF 1 after six hours.

AB - Crystals of a two-dimensional (2D) metal-organic framework (MOF) [Cd3(BTB)2(DEF)4]·2(DEF)0.5(1; BTB = benzene-1,3,5-tribenzolate; DEF =N,N'-diethylformamide) immersed in a solution oftrans-1,2-bis(4-pyridyl)ethylene (BPEE) yields an interpenetrated three-dimensional (3D) MOF of [Cd3(BTB)2(BPEE)(H2O)2]·(BPEE)·xSol (2). Crystals of MOF2, in turn, undergo a cascade conversion when immersed in DEF, yielding [Cd3(BTB)2(BPEE)1.8(DEF)0.9(H2O)0.8]·xSol (3a) over 100 seconds and [Cd3(BTB)2(BPEE)2(DEF)2]·xSol (4) after one hour, before finally shuttling back to MOF 1 after six hours.

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U2 - 10.1039/d0cc02420a

DO - 10.1039/d0cc02420a

M3 - Article

C2 - 32364556

AN - SCOPUS:85085707173

VL - 56

SP - 5877

EP - 5880

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 44

ER -