Aurophilicity in tetraphenylphosphonium 7,8-Bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-dibromo-digold(I)[PPh4][{(PPh 2)2-C2B9H10}(AuBr) 2]

Effendy, Peter C. Healy, Cassandra L. Noack, Brian W. Skelton, Allan H. White, David J. Young

Research output: Contribution to journalArticle

Abstract

Reactions of tetraphenylphosphonium dibromoaurate(I) with 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane in 2:1 ratio in acetone solution yields brown crystals shown to be the title compound. A single crystal X-ray study shows coordination of AuBr moieties by the phosphorus atoms of the ligand (Au-P 2.253(1), 2.246(1); Ag-Br 2.4041(7), 2.4067(7) Å), permitting a close Au⋯Au contact (2.9536(3)Å) with concomitant bending of the P-Au-Br arrays (173.99(4), 166.14(4)°) and a Br-Au⋯Au-Br torsion of 47.80(2)°.

Original languageEnglish
Pages (from-to)2689-2691
Number of pages3
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume633
Issue number15
DOIs
Publication statusPublished - Nov 2007
Externally publishedYes

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