Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols

Yao Cui, Jixian Wang, Lei Yu, Ying Xu, David J. Young, Haiyan Li, Hongxi Li

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Abstract

Solid supports functionalized with molecular metal catalysts combine many of the advantages of heterogeneous and homogeneous catalysis. A (NNN)Ru-incorporated porous organic polymer (POP-bp/bbpRuCl3) exhibited high catalytic efficiency and broad functional group tolerance in the C–C cross-coupling of secondary and primary alcohols to give β-alkylated secondary alcohols. This catalyst demonstrated excellent durability during successive recycling without leaching of Ru which is ascribed to the strong binding of the pincer ligands to the metal ions.

Original languageEnglish
Article number231
Pages (from-to)1-13
Number of pages13
JournalPolymers
Volume14
Issue number2
DOIs
Publication statusPublished - 7 Jan 2022

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