Abstract
The ZnII atom in the title compound, [ZnCl2(C 14H13N3)], is coordinated by a Cl 2N2 donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetra-hedral geometry relate to the restricted bite angle of the chelating ligand [N-Zn-N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C-H⋯Cl inter-actions, involving both Cl atoms, and π-π inter-actions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [inter-centroid distances = 3.655 (2) and 3.676 (2) Å].
| Original language | English |
|---|---|
| Pages (from-to) | m571-m572 |
| Number of pages | 2 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | E68 |
| Issue number | Part 5 |
| DOIs | |
| Publication status | Published - 1 May 2012 |
| Externally published | Yes |
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Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline- κN]zinc. / Najib, Muhd Hidayat Bin; Tan, Ai Ling; Young, David J.; Ng, Seik Weng; Tiekink, Edward R T.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. E68, No. Part 5, 01.05.2012, p. m571-m572.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN2)quinoline- κN]zinc
AU - Najib, Muhd Hidayat Bin
AU - Tan, Ai Ling
AU - Young, David J.
AU - Ng, Seik Weng
AU - Tiekink, Edward R T
PY - 2012/5/1
Y1 - 2012/5/1
N2 - The ZnII atom in the title compound, [ZnCl2(C 14H13N3)], is coordinated by a Cl 2N2 donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetra-hedral geometry relate to the restricted bite angle of the chelating ligand [N-Zn-N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C-H⋯Cl inter-actions, involving both Cl atoms, and π-π inter-actions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [inter-centroid distances = 3.655 (2) and 3.676 (2) Å].
AB - The ZnII atom in the title compound, [ZnCl2(C 14H13N3)], is coordinated by a Cl 2N2 donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetra-hedral geometry relate to the restricted bite angle of the chelating ligand [N-Zn-N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C-H⋯Cl inter-actions, involving both Cl atoms, and π-π inter-actions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [inter-centroid distances = 3.655 (2) and 3.676 (2) Å].
UR - http://www.scopus.com/inward/record.url?scp=84860749751&partnerID=8YFLogxK
U2 - 10.1107/S1600536812014390
DO - 10.1107/S1600536812014390
M3 - Article
VL - E68
SP - m571-m572
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 1600-5368
IS - Part 5
ER -