(E)-O-Ethyl N-(4-nitrophenyl)thiocarbamate

Ronald E. Benson, Grant A. Broker, Lee M. Daniels, Edward R.T. Tiekink, James L. Wardell, David J. Young

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The title compound, C9H10N2O3S, is effectively planar, adopts an E conformation about the central C-N bond and exists in the thione form. N-H⋯S and C-H⋯O hydrogen bonds link the molecules into ribbons. Layers of ribbons are connected to adjacent layers via C-H⋯O interactions. The crystal is a non-merohedral twin, with the twin law describing a rotation of 180° around the [1̄00] direction.

Original languageEnglish
Pages (from-to)o4106-o4108
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE62
Issue numberPart 9
DOIs
Publication statusPublished - 1 Sep 2006
Externally publishedYes

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Thiocarbamates
Thiones
ribbons
Conformations
Hydrogen bonds
Crystals
Molecules
hydrogen bonds
crystals
molecules
interactions
Direction compound
4-nitrophenyl

Cite this

Benson, R. E., Broker, G. A., Daniels, L. M., Tiekink, E. R. T., Wardell, J. L., & Young, D. J. (2006). (E)-O-Ethyl N-(4-nitrophenyl)thiocarbamate. Acta Crystallographica Section E: Structure Reports Online, E62(Part 9), o4106-o4108. https://doi.org/10.1107/S1600536806033058
Benson, Ronald E. ; Broker, Grant A. ; Daniels, Lee M. ; Tiekink, Edward R.T. ; Wardell, James L. ; Young, David J. / (E)-O-Ethyl N-(4-nitrophenyl)thiocarbamate. In: Acta Crystallographica Section E: Structure Reports Online. 2006 ; Vol. E62, No. Part 9. pp. o4106-o4108.
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Benson, RE, Broker, GA, Daniels, LM, Tiekink, ERT, Wardell, JL & Young, DJ 2006, '(E)-O-Ethyl N-(4-nitrophenyl)thiocarbamate', Acta Crystallographica Section E: Structure Reports Online, vol. E62, no. Part 9, pp. o4106-o4108. https://doi.org/10.1107/S1600536806033058

(E)-O-Ethyl N-(4-nitrophenyl)thiocarbamate. / Benson, Ronald E.; Broker, Grant A.; Daniels, Lee M.; Tiekink, Edward R.T.; Wardell, James L.; Young, David J.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. E62, No. Part 9, 01.09.2006, p. o4106-o4108.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

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AU - Broker, Grant A.

AU - Daniels, Lee M.

AU - Tiekink, Edward R.T.

AU - Wardell, James L.

AU - Young, David J.

PY - 2006/9/1

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AB - The title compound, C9H10N2O3S, is effectively planar, adopts an E conformation about the central C-N bond and exists in the thione form. N-H⋯S and C-H⋯O hydrogen bonds link the molecules into ribbons. Layers of ribbons are connected to adjacent layers via C-H⋯O interactions. The crystal is a non-merohedral twin, with the twin law describing a rotation of 180° around the [1̄00] direction.

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