Abstract
Contrary to expectations, the high pressure (9 kbar, 30°C) mediated addition of allyltrimethylstannane (2) to α-amino aldehydes (1) proceeds via an anti - Felkin - Anh mode to provide predominantly (60-88%) syn homoallylic alcohols. The diastereoselectivity of this reaction is dependent on the amino aldehyde side chain.
Original language | English |
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Pages (from-to) | 581-582 |
Number of pages | 2 |
Journal | Main Group Metal Chemistry |
Volume | 20 |
Issue number | 9 |
DOIs | |
Publication status | Published - 1 Sep 1997 |
Externally published | Yes |