In Situ Generation of Bifunctional Fe-Doped MoS2 Nanocanopies for Efficient Electrocatalytic Water Splitting

Jiang Yan Xue, Fei Long Li, Zhong Yin Zhao, Cong Li, Chun Yan Ni, Hong Wei Gu, David James Young, Jian Ping Lang

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Design and synthesis of non-noble metal electrocatalysts with high activity and durability for the electrolysis of water is of great significance for energy conversion and storage. In this work, we prepared a series of Fe-doped MoS2 nanomaterials by simple one-pot solvothermal reactions of (NH4)2MoS4 with FeCl3·6H2O. An optimized working electrode of Fe-MoS2-5 displayed high hydrogen evolution reaction (HER) activity with a relatively small overpotential of 173 mV to achieve a current density of 10 mA cm-2 in 0.5 M H2SO4, along with no significant change in catalytic performance even after 1000 cyclic voltammetry (CV) cycles. Fe-MoS2 nanoparticles on nickel foam (NF; denoted as Fe-MoS2/NF) exhibited an overpotential of 230 mV at 20 mA cm-2 for the oxygen evolution reaction (OER) and 153 mV at 10 mA cm-2 for the HER in 1.0 M KOH electrolyte. Fe-MoS2/NF was stable for more than 140 h under these conditions. Furthermore, the two electrode system of Fe-MoS2/NF (anode)//Fe-MoS2/NF (cathode) electrodes demonstrated excellent electrocatalytic activity toward overall water splitting with a low potential of 1.52 V at 10 mA cm-2 in 1.0 M KOH electrolyte. ©

    Original languageEnglish
    Pages (from-to)11202-11209
    Number of pages8
    JournalInorganic Chemistry
    Volume58
    Issue number16
    Early online date6 Aug 2019
    DOIs
    Publication statusPublished - 19 Aug 2019

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