Large-Scale, Bottom-Up Synthesis of Binary Metal–Organic Framework Nanosheets for Efficient Water Oxidation

Fei Long Li, Pengtang Wang, Xiaoqing Huang, David James Young, Hui Fang Wang, Pierre Braunstein, Jian Ping Lang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Ultrathin metal–organic framework (MOF) nanosheets (NSs) offer potential for many applications, but the synthetic strategies are largely limited to top-down, low-yield exfoliation methods. Herein, Ni–M–MOF (M=Fe, Al, Co, Mn, Zn, and Cd) NSs are reported with a thickness of only several atomic layers, prepared by a large-scale, bottom-up solvothermal method. The solvent mixture of N,N-dimethylacetamide and water plays key role in controlling the formation of these two-dimensional MOF NSs. The MOF NSs can be directly used as efficient electrocatalysts for the oxygen evolution reaction, in which the Ni–Fe–MOF NSs deliver a current density of 10 mA cm −2 at a low overpotential of 221 mV with a small Tafel slope of 56.0 mV dec −1 , and exhibit excellent stability for at least 20 h without obvious activity decay. Density functional theory calculations on the energy barriers for OER occurring at different metal sites confirm that Fe is the active site for OER at Ni–Fe–MOF NSs.

Original languageEnglish
Pages (from-to)7051-7056
Number of pages6
JournalAngewandte Chemie - International Edition
Volume58
Issue number21
Early online date26 Mar 2019
DOIs
Publication statusPublished - 20 May 2019

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Nanosheets
Oxidation
Water
Electrocatalysts
Energy barriers
Density functional theory
Current density
Metals
Oxygen

Cite this

Li, Fei Long ; Wang, Pengtang ; Huang, Xiaoqing ; Young, David James ; Wang, Hui Fang ; Braunstein, Pierre ; Lang, Jian Ping. / Large-Scale, Bottom-Up Synthesis of Binary Metal–Organic Framework Nanosheets for Efficient Water Oxidation. In: Angewandte Chemie - International Edition. 2019 ; Vol. 58, No. 21. pp. 7051-7056.
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abstract = "Ultrathin metal–organic framework (MOF) nanosheets (NSs) offer potential for many applications, but the synthetic strategies are largely limited to top-down, low-yield exfoliation methods. Herein, Ni–M–MOF (M=Fe, Al, Co, Mn, Zn, and Cd) NSs are reported with a thickness of only several atomic layers, prepared by a large-scale, bottom-up solvothermal method. The solvent mixture of N,N-dimethylacetamide and water plays key role in controlling the formation of these two-dimensional MOF NSs. The MOF NSs can be directly used as efficient electrocatalysts for the oxygen evolution reaction, in which the Ni–Fe–MOF NSs deliver a current density of 10 mA cm −2 at a low overpotential of 221 mV with a small Tafel slope of 56.0 mV dec −1 , and exhibit excellent stability for at least 20 h without obvious activity decay. Density functional theory calculations on the energy barriers for OER occurring at different metal sites confirm that Fe is the active site for OER at Ni–Fe–MOF NSs.",
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Large-Scale, Bottom-Up Synthesis of Binary Metal–Organic Framework Nanosheets for Efficient Water Oxidation. / Li, Fei Long; Wang, Pengtang; Huang, Xiaoqing; Young, David James; Wang, Hui Fang; Braunstein, Pierre; Lang, Jian Ping.

In: Angewandte Chemie - International Edition, Vol. 58, No. 21, 20.05.2019, p. 7051-7056.

Research output: Contribution to journalArticleResearchpeer-review

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