Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties

Mei Yang, Xin Yi Wu, Hui Fang Wang, David James Young, Zhi Gang Ren, Jian Ping Lang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.

Original languageEnglish
Pages (from-to)6599-6602
Number of pages4
JournalChemical Communications
Volume55
Issue number46
DOIs
Publication statusPublished - Jun 2019

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phosphine
Tetramethylphenylenediamine
Silver
Cations
Polymers
Positive ions
Ligands
Charge transfer
Metals
Photocurrents
Discrete Fourier transforms
Paramagnetic resonance
Spectroscopy

Cite this

Yang, Mei ; Wu, Xin Yi ; Wang, Hui Fang ; Young, David James ; Ren, Zhi Gang ; Lang, Jian Ping. / Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties. In: Chemical Communications. 2019 ; Vol. 55, No. 46. pp. 6599-6602.
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Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties. / Yang, Mei; Wu, Xin Yi; Wang, Hui Fang; Young, David James; Ren, Zhi Gang; Lang, Jian Ping.

In: Chemical Communications, Vol. 55, No. 46, 06.2019, p. 6599-6602.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Yang, Mei

AU - Wu, Xin Yi

AU - Wang, Hui Fang

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AU - Ren, Zhi Gang

AU - Lang, Jian Ping

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