Abstract
Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.
| Original language | English |
|---|---|
| Pages (from-to) | 6599-6602 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 46 |
| DOIs | |
| Publication status | Published - Jun 2019 |
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Yang, M., Wu, X. Y., Wang, H. F., Young, D. J., Ren, Z. G., & Lang, J. P. (2019). Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties. Chemical Communications, 55(46), 6599-6602. https://doi.org/10.1039/c9cc01711a