Abstract
Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.
| Original language | English |
|---|---|
| Pages (from-to) | 6599-6602 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 46 |
| DOIs | |
| Publication status | Published - Jun 2019 |
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Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties. / Yang, Mei; Wu, Xin Yi; Wang, Hui Fang; Young, David James; Ren, Zhi Gang; Lang, Jian Ping.
In: Chemical Communications, Vol. 55, No. 46, 06.2019, p. 6599-6602.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties
AU - Yang, Mei
AU - Wu, Xin Yi
AU - Wang, Hui Fang
AU - Young, David James
AU - Ren, Zhi Gang
AU - Lang, Jian Ping
PY - 2019/6
Y1 - 2019/6
N2 - Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.
AB - Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.
UR - http://www.scopus.com/inward/record.url?scp=85066820096&partnerID=8YFLogxK
U2 - 10.1039/c9cc01711a
DO - 10.1039/c9cc01711a
M3 - Article
VL - 55
SP - 6599
EP - 6602
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 46
ER -