Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties

Mei Yang, Xin Yi Wu, Hui Fang Wang, David James Young, Zhi Gang Ren, Jian Ping Lang

Research output: Contribution to journalArticle

Abstract

Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.

Original languageEnglish
Pages (from-to)6599-6602
Number of pages4
JournalChemical Communications
Volume55
Issue number46
DOIs
Publication statusPublished - Jun 2019

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