Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties

Mei Yang; Xin Yi Wu; Hui Fang Wang; David James Young; Zhi Gang Ren; Jian Ping Lang

doi:10.1039/c9cc01711a

Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties

Mei Yang, Xin Yi Wu, Hui Fang Wang, David James Young, Zhi Gang Ren, Jian Ping Lang

CDU College of Engineering, IT and Environment

Research output: Contribution to journal › Article › peer-review

Abstract

Tetraphosphine ligand dpppda reacts with AgNO₃ to generate two 1D coordination polymers containing cubic and chair-like [Ag₄(NO₃)₄] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda⁺, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher Ag^I → Ag potentials and good photocurrent responses.

Original language	English
Pages (from-to)	6599-6602
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	46
DOIs	https://doi.org/10.1039/c9cc01711a
Publication status	Published - Jun 2019

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title = "Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties",

abstract = "Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.",

author = "Mei Yang and Wu, {Xin Yi} and Wang, {Hui Fang} and Young, {David James} and Ren, {Zhi Gang} and Lang, {Jian Ping}",

year = "2019",

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doi = "10.1039/c9cc01711a",

language = "English",

volume = "55",

pages = "6599--6602",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry (RSC)",

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T1 - Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties

AU - Yang, Mei

AU - Wu, Xin Yi

AU - Wang, Hui Fang

AU - Young, David James

AU - Ren, Zhi Gang

AU - Lang, Jian Ping

PY - 2019/6

Y1 - 2019/6

N2 - Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.

AB - Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda+, a Wurster's blue-like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag potentials and good photocurrent responses.

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U2 - 10.1039/c9cc01711a

DO - 10.1039/c9cc01711a

M3 - Article

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EP - 6602

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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ER -

Novel silver-phosphine coordination polymers incorporating a Wurster's blue-like radical cation with enhanced photoelectric properties

Abstract

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