Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5

Naseer A. Khan, Eric M. Kennedy, Bogdan Z. Dlugogorski, Adesoji A. Adesina, Michael Stockenhuber

Research output: Contribution to journalArticle

Abstract

Synthesis gas (CO + H2) is a versatile and significant resource. In this communication we show that cobalt loaded on ZSM-5 (Co-ZSM-5) catalyses the formation of synthesis gas from CH4, under partial oxidation conditions using N2O as oxidant. With O2 as oxidant over the same Co-ZSM-5 catalyst, cobalt on alumina and Fe-ZSM-5, only COx and H2O are formed. Isolated Co2 + sites in the ZSM-5 support are proposed as the active sites for H2 (synthesis gas) formation.

Original languageEnglish
Pages (from-to)42-46
Number of pages5
JournalCatalysis Communications
Volume53
Issue numberAugust
Early online date24 Apr 2014
DOIs
Publication statusPublished - 5 Aug 2014
Externally publishedYes

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Khan, N. A., Kennedy, E. M., Dlugogorski, B. Z., Adesina, A. A., & Stockenhuber, M. (2014). Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5. Catalysis Communications, 53(August), 42-46. https://doi.org/10.1016/j.catcom.2014.04.012