Polymeric anhydrous sodium 2-amino-benzensulfonate

Graham Smith; Urs D. Wermuth; David J. Young; Peter C. Healy

doi:10.1107/S1600536804011456

Polymeric anhydrous sodium 2-amino-benzensulfonate

Graham Smith, Urs D. Wermuth, David J. Young, Peter C. Healy

Research output: Contribution to journal › Article

Abstract

The crystal structure of anhydrous sodium 2-aminobenzene-sulfonate, [Na(C₆H₆NO₃S)]_n, reveals the presence of a two-dimensional sandwich polymer structure based on a distorted octahedral six-coordinate NaO₅N repeating unit. O-Donor atoms are from five different sulfonate groups [Na-O = 2.294 (3)-2.532 (3) Å] and an amine nitrogen [Na-N = 2.572 (3) Å], completing a six-membered chelate ring including Na. Hydrogen bonds also stabilize the core structure. The outer layers of the sandwich comprise the unassociated benzene rings.

Original language	English
Pages (from-to)	m836-m838
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	E60
Issue number	Part 6
DOIs	https://doi.org/10.1107/S1600536804011456
Publication status	Published - 1 Jun 2004
Externally published	Yes

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title = "Polymeric anhydrous sodium 2-amino-benzensulfonate",

abstract = "The crystal structure of anhydrous sodium 2-aminobenzene-sulfonate, [Na(C6H6NO3S)]n, reveals the presence of a two-dimensional sandwich polymer structure based on a distorted octahedral six-coordinate NaO5N repeating unit. O-Donor atoms are from five different sulfonate groups [Na-O = 2.294 (3)-2.532 (3) {\AA}] and an amine nitrogen [Na-N = 2.572 (3) {\AA}], completing a six-membered chelate ring including Na. Hydrogen bonds also stabilize the core structure. The outer layers of the sandwich comprise the unassociated benzene rings.",

author = "Graham Smith and Wermuth, {Urs D.} and Young, {David J.} and Healy, {Peter C.}",

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T1 - Polymeric anhydrous sodium 2-amino-benzensulfonate

AU - Smith, Graham

AU - Wermuth, Urs D.

AU - Young, David J.

AU - Healy, Peter C.

PY - 2004/6/1

Y1 - 2004/6/1

N2 - The crystal structure of anhydrous sodium 2-aminobenzene-sulfonate, [Na(C6H6NO3S)]n, reveals the presence of a two-dimensional sandwich polymer structure based on a distorted octahedral six-coordinate NaO5N repeating unit. O-Donor atoms are from five different sulfonate groups [Na-O = 2.294 (3)-2.532 (3) Å] and an amine nitrogen [Na-N = 2.572 (3) Å], completing a six-membered chelate ring including Na. Hydrogen bonds also stabilize the core structure. The outer layers of the sandwich comprise the unassociated benzene rings.

AB - The crystal structure of anhydrous sodium 2-aminobenzene-sulfonate, [Na(C6H6NO3S)]n, reveals the presence of a two-dimensional sandwich polymer structure based on a distorted octahedral six-coordinate NaO5N repeating unit. O-Donor atoms are from five different sulfonate groups [Na-O = 2.294 (3)-2.532 (3) Å] and an amine nitrogen [Na-N = 2.572 (3) Å], completing a six-membered chelate ring including Na. Hydrogen bonds also stabilize the core structure. The outer layers of the sandwich comprise the unassociated benzene rings.

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DO - 10.1107/S1600536804011456

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JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

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