Recent advances in Co-catalyzed C–C and C–N bond formation via ADC and ATH reactions

Meng Juan Zhang; Xiao Lan Ge; David J. Young; Hong Xi Li

doi:10.1016/j.tet.2021.132309

Recent advances in Co-catalyzed C–C and C–N bond formation via ADC and ATH reactions

Meng Juan Zhang, Xiao Lan Ge, David J. Young, Hong Xi Li

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Scarce precious metals commonly adopted for crucial technologies such as catalysis can potentially be replaced with inexpensive, earth-abundant metals. Cobalt is gaining attention in this respect because of its distinctive redox chemistry that is suited to catalyzing the formation of C–C and C–N bonds. Two recently developed examples are cobalt-catalyzed acceptorless dehydrogenative coupling (ADC) and auto-transfer-hydrogenative (ATH) reactions for the reliable and mild construction of these bonds. Advances in both classes of reaction are herein reviewed (2013-present).

Original language	English
Article number	132309
Pages (from-to)	1-9
Number of pages	9
Journal	Tetrahedron
Volume	93
Early online date	29 Jun 2021
DOIs	https://doi.org/10.1016/j.tet.2021.132309
Publication status	Published - 30 Jul 2021

Bibliographical note

Funding Information:
We thank the Natural Science Research Key Projects of Anhui Province Universities ( KJ2020A0774 ) and the National Natural Science Foundation of China ( 21771131 and 21971182 ).

Publisher Copyright:
© 2021 Elsevier Ltd

Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.

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title = "Recent advances in Co-catalyzed C–C and C–N bond formation via ADC and ATH reactions",

abstract = "Scarce precious metals commonly adopted for crucial technologies such as catalysis can potentially be replaced with inexpensive, earth-abundant metals. Cobalt is gaining attention in this respect because of its distinctive redox chemistry that is suited to catalyzing the formation of C–C and C–N bonds. Two recently developed examples are cobalt-catalyzed acceptorless dehydrogenative coupling (ADC) and auto-transfer-hydrogenative (ATH) reactions for the reliable and mild construction of these bonds. Advances in both classes of reaction are herein reviewed (2013-present).",

keywords = "Acceptorless dehydrogenative coupling, Auto-transfer-hydrogen, C-N bond formation, Cobalt catalyst, C–C bond formation",

author = "Zhang, {Meng Juan} and Ge, {Xiao Lan} and Young, {David J.} and Li, {Hong Xi}",

note = "Funding Information: We thank the Natural Science Research Key Projects of Anhui Province Universities ( KJ2020A0774 ) and the National Natural Science Foundation of China ( 21771131 and 21971182 ). Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

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doi = "10.1016/j.tet.2021.132309",

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T1 - Recent advances in Co-catalyzed C–C and C–N bond formation via ADC and ATH reactions

AU - Zhang, Meng Juan

AU - Ge, Xiao Lan

AU - Young, David J.

AU - Li, Hong Xi

N1 - Funding Information: We thank the Natural Science Research Key Projects of Anhui Province Universities ( KJ2020A0774 ) and the National Natural Science Foundation of China ( 21771131 and 21971182 ). Publisher Copyright: © 2021 Elsevier Ltd Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/7/30

Y1 - 2021/7/30

N2 - Scarce precious metals commonly adopted for crucial technologies such as catalysis can potentially be replaced with inexpensive, earth-abundant metals. Cobalt is gaining attention in this respect because of its distinctive redox chemistry that is suited to catalyzing the formation of C–C and C–N bonds. Two recently developed examples are cobalt-catalyzed acceptorless dehydrogenative coupling (ADC) and auto-transfer-hydrogenative (ATH) reactions for the reliable and mild construction of these bonds. Advances in both classes of reaction are herein reviewed (2013-present).

AB - Scarce precious metals commonly adopted for crucial technologies such as catalysis can potentially be replaced with inexpensive, earth-abundant metals. Cobalt is gaining attention in this respect because of its distinctive redox chemistry that is suited to catalyzing the formation of C–C and C–N bonds. Two recently developed examples are cobalt-catalyzed acceptorless dehydrogenative coupling (ADC) and auto-transfer-hydrogenative (ATH) reactions for the reliable and mild construction of these bonds. Advances in both classes of reaction are herein reviewed (2013-present).

KW - Acceptorless dehydrogenative coupling

KW - Auto-transfer-hydrogen

KW - C-N bond formation

KW - Cobalt catalyst

KW - C–C bond formation

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U2 - 10.1016/j.tet.2021.132309

DO - 10.1016/j.tet.2021.132309

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SN - 0040-4020

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SP - 1

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JO - Tetrahedron

JF - Tetrahedron

M1 - 132309

ER -

Recent advances in Co-catalyzed C–C and C–N bond formation via ADC and ATH reactions

Abstract

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