TY - JOUR
T1 - Rice grain-shaped TiO2–CNT composite—A functional material with a novel morphology for dye-sensitized solar cells
AU - Peining, Zhu
AU - Nair, A Sreekumaran
AU - Shengyuan, Yang
AU - Shengjie, Peng
AU - Elumalai, Naveen Kumar
AU - Ramakrishna, Seeram
PY - 2012
Y1 - 2012
N2 - Titanium dioxide-multiwalled carbon nanotube (denoted as TiO2–CNT) nanocomposites with a novel rice-grains nanostructure are synthesized by electrospinning and subsequent high temperature sintering. The rice grain-shaped TiO2 is single crystalline with a large surface area and the single crystallinity is retained in the TiO2–CNT composite as well. At very low CNT loadings (0.1–0.3 wt% of TiO2), the rice grain shape remains unchanged while at high CNT concentrations (8 wt%), the morphology distorts with CNTs sticking out of the rice-grain shape. The optimum concentration of CNTs in the TiO2 matrix for best performance in dye-sensitized solar cells (DSCs) is found to be 0.2 wt%, which shows a 32% enhancement in the energy conversion efficiency. The electrochemical impedance spectroscopy (EIS) and the incident photon-to-electron conversion efficiency (IPCE) measurements show that the charge transfer and collection are improved by the incorporation of CNTs into the rice grain-shaped TiO2 network. We believe that this facile one-pot method for the synthesis of the rice-grain shaped TiO2–CNT composites with high surface area and single crystallinity offers an attractive means for the mass-scale fabrication of the nanostructures for DSCs since electrospinning is a simple, cost-effective and scalable means for the commercial scale fabrication of one-dimensional nanostructures.
AB - Titanium dioxide-multiwalled carbon nanotube (denoted as TiO2–CNT) nanocomposites with a novel rice-grains nanostructure are synthesized by electrospinning and subsequent high temperature sintering. The rice grain-shaped TiO2 is single crystalline with a large surface area and the single crystallinity is retained in the TiO2–CNT composite as well. At very low CNT loadings (0.1–0.3 wt% of TiO2), the rice grain shape remains unchanged while at high CNT concentrations (8 wt%), the morphology distorts with CNTs sticking out of the rice-grain shape. The optimum concentration of CNTs in the TiO2 matrix for best performance in dye-sensitized solar cells (DSCs) is found to be 0.2 wt%, which shows a 32% enhancement in the energy conversion efficiency. The electrochemical impedance spectroscopy (EIS) and the incident photon-to-electron conversion efficiency (IPCE) measurements show that the charge transfer and collection are improved by the incorporation of CNTs into the rice grain-shaped TiO2 network. We believe that this facile one-pot method for the synthesis of the rice-grain shaped TiO2–CNT composites with high surface area and single crystallinity offers an attractive means for the mass-scale fabrication of the nanostructures for DSCs since electrospinning is a simple, cost-effective and scalable means for the commercial scale fabrication of one-dimensional nanostructures.
UR - http://www.scopus.com/inward/record.url?scp=84856569688&partnerID=8YFLogxK
U2 - 10.1016/j.jphotochem.2012.01.002
DO - 10.1016/j.jphotochem.2012.01.002
M3 - Article
VL - 231
SP - 9
EP - 18
JO - Journal of Photochemistry and Photobiology A: Chemistry
JF - Journal of Photochemistry and Photobiology A: Chemistry
SN - 1010-6030
IS - 1
ER -