Selecting Environmental Water Tracers to Understand Groundwater around Mines: Opportunities and Limitations

Underground mining operations have the potential to alter groundwater systems and facilitate hydraulic connections between surface water and groundwater. The nature and degree of these interactions need to be evaluated to identify mining risks to surrounding water resources and to predict potential operational effects and environmental impacts, such as hydraulic stress on local surface waters. Environmental water tracers (EWTs) are commonly used to study such interactions in mine water and hydrogeological studies. However, the opportunities presented by EWTs could be more widely utilised to benefit the mining industry and the environment. Some of the challenges faced include the lack of practical frameworks, the need for more examples of EWTs applications in mining, and the possibility of complex interpretation of tracer results. This paper reviews previous studies that have applied EWTs in groundwater systems within or near mine sites, mostly from Australia, China, and India. The EWTs used in these studies include water quality parameters, major ions, stable isotopes, radioisotopes, and dissolved gases. The opportunities of applying multiple EWTs to identify water sources, mixing, and determine recharge rates and groundwater residence times are discussed. Limitations of different EWTs in terms of their capabilities, reliability, cost of analysis, effort, and processing times are reviewed. Steps for selecting suitable EWTs for specific mine hydrogeology assessments should be commensurate with the risks. Finally, this paper provides an overview of suitable EWTs that will be a useful contribution to appropriate water resource management decisions around mines.