Abstract
The Lewis acids CH3SiCl3 (0.33 - 1.0 equivalents) and (CH3O)2SiCH3Cl (1.0 equivalent) promote the addition of aldehydes to allylstannanes to yield the homoallyl silyl ethers 1a, 1b, 3 - 5. These reactions do not proceed via an initial transmetallation.
| Original language | English |
|---|---|
| Pages (from-to) | 1365-1368 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 33 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 3 Mar 1992 |
| Externally published | Yes |
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Cite this
Marshall, R., & Young, D. J. (1992). Silicon Lewis acids promote the addition of aldehydes to allylstannanes without transmetallation. Tetrahedron Letters, 33(10), 1365-1368. https://doi.org/10.1016/S0040-4039(00)91624-1