Smoothing the single-crystal to single-crystal conversions of a two-dimensional metal-organic framework

Via the hetero-metal doping of the linear trimetallic secondary building unit

Meng Yao Chao, Jing Chen, David J. Young, Wen Hua Zhang, Jian Ping Lang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The two-dimensional (2D) metal-organic framework (MOF) [Cd2.25Co0.75(BTB)2(DEF)4]·2(DEF)0.5 (1a, BTB = benzene-1,3,5-tribenzolate; DEF = N,N′-diethylformamide) featuring linear trimetallic cluster secondary building units (SBUs) and replaceable DEF solvates reacts smoothly with dipyridyl ligands DPS, DPDS, and BIPY (DPS = 4,4′-dipyridyl sulfide; DPDS = 4,4′-dipyridyl disulfide; BIPY = 4,4′-bipyridine), yielding three-dimensional (3D) non-interpenetrated [Cd2.25Co0.75(BTB)2(DPS)2]·xSol (2) and [Cd2.25Co0.75(BTB)2(DPDS)2]·xSol (3), and interpenetrated [Cd2.25Co0.75(BTB)2(BIPY)(H2O)2]·xSol (4). The smooth conversion of 1a to 3 contrasts the drastic single-crystal to single-crystal (SCSC) conversion observed for the homometallic [Cd3(BTB)2(DEF)4]·2(DEF)0.5 (1b), presumably due to the presence of the relatively Lewis acidic Co2+ that lessens the propensity for binding by soft dipyridyl donors. Activated samples of 2-4 showed no obvious absorption of N2 at 77 K, but reversible type I uptake of CO2 at 195 K.

Original languageEnglish
Pages (from-to)13722-13729
Number of pages8
JournalDalton Transactions
Volume47
Issue number38
DOIs
Publication statusPublished - 14 Oct 2018
Externally publishedYes

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Metals
Doping (additives)
Single crystals
Sulfides
Benzene
Disulfides
butyl phosphorotrithioate
Ligands

Cite this

@article{7644df50277c494cbdb620dc110bd459,
title = "Smoothing the single-crystal to single-crystal conversions of a two-dimensional metal-organic framework: Via the hetero-metal doping of the linear trimetallic secondary building unit",
abstract = "The two-dimensional (2D) metal-organic framework (MOF) [Cd2.25Co0.75(BTB)2(DEF)4]·2(DEF)0.5 (1a, BTB = benzene-1,3,5-tribenzolate; DEF = N,N′-diethylformamide) featuring linear trimetallic cluster secondary building units (SBUs) and replaceable DEF solvates reacts smoothly with dipyridyl ligands DPS, DPDS, and BIPY (DPS = 4,4′-dipyridyl sulfide; DPDS = 4,4′-dipyridyl disulfide; BIPY = 4,4′-bipyridine), yielding three-dimensional (3D) non-interpenetrated [Cd2.25Co0.75(BTB)2(DPS)2]·xSol (2) and [Cd2.25Co0.75(BTB)2(DPDS)2]·xSol (3), and interpenetrated [Cd2.25Co0.75(BTB)2(BIPY)(H2O)2]·xSol (4). The smooth conversion of 1a to 3 contrasts the drastic single-crystal to single-crystal (SCSC) conversion observed for the homometallic [Cd3(BTB)2(DEF)4]·2(DEF)0.5 (1b), presumably due to the presence of the relatively Lewis acidic Co2+ that lessens the propensity for binding by soft dipyridyl donors. Activated samples of 2-4 showed no obvious absorption of N2 at 77 K, but reversible type I uptake of CO2 at 195 K.",
author = "Chao, {Meng Yao} and Jing Chen and Young, {David J.} and Zhang, {Wen Hua} and Lang, {Jian Ping}",
year = "2018",
month = "10",
day = "14",
doi = "10.1039/c8dt02813c",
language = "English",
volume = "47",
pages = "13722--13729",
journal = "Dalton Transactions: an international journal of inorganic chemistry",
issn = "1477-9226",
publisher = "Royal Society of Chemistry (RSC)",
number = "38",

}

Smoothing the single-crystal to single-crystal conversions of a two-dimensional metal-organic framework : Via the hetero-metal doping of the linear trimetallic secondary building unit. / Chao, Meng Yao; Chen, Jing; Young, David J.; Zhang, Wen Hua; Lang, Jian Ping.

In: Dalton Transactions, Vol. 47, No. 38, 14.10.2018, p. 13722-13729.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Smoothing the single-crystal to single-crystal conversions of a two-dimensional metal-organic framework

T2 - Via the hetero-metal doping of the linear trimetallic secondary building unit

AU - Chao, Meng Yao

AU - Chen, Jing

AU - Young, David J.

AU - Zhang, Wen Hua

AU - Lang, Jian Ping

PY - 2018/10/14

Y1 - 2018/10/14

N2 - The two-dimensional (2D) metal-organic framework (MOF) [Cd2.25Co0.75(BTB)2(DEF)4]·2(DEF)0.5 (1a, BTB = benzene-1,3,5-tribenzolate; DEF = N,N′-diethylformamide) featuring linear trimetallic cluster secondary building units (SBUs) and replaceable DEF solvates reacts smoothly with dipyridyl ligands DPS, DPDS, and BIPY (DPS = 4,4′-dipyridyl sulfide; DPDS = 4,4′-dipyridyl disulfide; BIPY = 4,4′-bipyridine), yielding three-dimensional (3D) non-interpenetrated [Cd2.25Co0.75(BTB)2(DPS)2]·xSol (2) and [Cd2.25Co0.75(BTB)2(DPDS)2]·xSol (3), and interpenetrated [Cd2.25Co0.75(BTB)2(BIPY)(H2O)2]·xSol (4). The smooth conversion of 1a to 3 contrasts the drastic single-crystal to single-crystal (SCSC) conversion observed for the homometallic [Cd3(BTB)2(DEF)4]·2(DEF)0.5 (1b), presumably due to the presence of the relatively Lewis acidic Co2+ that lessens the propensity for binding by soft dipyridyl donors. Activated samples of 2-4 showed no obvious absorption of N2 at 77 K, but reversible type I uptake of CO2 at 195 K.

AB - The two-dimensional (2D) metal-organic framework (MOF) [Cd2.25Co0.75(BTB)2(DEF)4]·2(DEF)0.5 (1a, BTB = benzene-1,3,5-tribenzolate; DEF = N,N′-diethylformamide) featuring linear trimetallic cluster secondary building units (SBUs) and replaceable DEF solvates reacts smoothly with dipyridyl ligands DPS, DPDS, and BIPY (DPS = 4,4′-dipyridyl sulfide; DPDS = 4,4′-dipyridyl disulfide; BIPY = 4,4′-bipyridine), yielding three-dimensional (3D) non-interpenetrated [Cd2.25Co0.75(BTB)2(DPS)2]·xSol (2) and [Cd2.25Co0.75(BTB)2(DPDS)2]·xSol (3), and interpenetrated [Cd2.25Co0.75(BTB)2(BIPY)(H2O)2]·xSol (4). The smooth conversion of 1a to 3 contrasts the drastic single-crystal to single-crystal (SCSC) conversion observed for the homometallic [Cd3(BTB)2(DEF)4]·2(DEF)0.5 (1b), presumably due to the presence of the relatively Lewis acidic Co2+ that lessens the propensity for binding by soft dipyridyl donors. Activated samples of 2-4 showed no obvious absorption of N2 at 77 K, but reversible type I uptake of CO2 at 195 K.

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U2 - 10.1039/c8dt02813c

DO - 10.1039/c8dt02813c

M3 - Article

VL - 47

SP - 13722

EP - 13729

JO - Dalton Transactions: an international journal of inorganic chemistry

JF - Dalton Transactions: an international journal of inorganic chemistry

SN - 1477-9226

IS - 38

ER -