Abstract
Tetraallylic, tetraallenic and tetrapropargylic stannanes (0.25 eq) react with aldehydes in methanol to provide unsaturated alcohols. These reactions proceed exclusively with allylic rearrangement for tetra(2-butenyl)tin 2b and tetra(1,2-butadienyl)tin 5e and predominantly with allylic rearrangement for tetrapropadienyltin Sc and tetra(2-butynyl)tin 6e. The corresponding TFA catalysed reactions of dimethyl acetals with Sc and 6e are highly regioselective with allylic rearrangement.
| Original language | English |
|---|---|
| Pages (from-to) | 909-911 |
| Number of pages | 3 |
| Journal | Synlett |
| Volume | 1998 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 1998 |
| Externally published | Yes |
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McCluskey, A., Muderawari, I. W., Muntari, & Young, D. J. (1998). Solvent assisted addition of tetraallylic, tetraallenic and tetrapropargylic stannanes to aldehydes and acetals. Synlett, 1998(8), 909-911. https://doi.org/10.1055/s-1998-1807