TY - JOUR
T1 - Stoichiometric sensitivity and structural diversity in click-active copper(I) N,S-heterocyclic carbene complexes
AU - Han, Xiaoyan
AU - Weng, Zhiqiang
AU - Young, David James
AU - Jin, Guo Xin
AU - Andy Hor, T. S.
PY - 2014/1/21
Y1 - 2014/1/21
N2 - A series of novel Cu(I) N,S-heterocyclic carbene (NSHC) complexes [Cu(μ-Br)(NSHC)]2, [Cu(μ-X)(NSHC)]4 (X = Br or I), [(NSHC)2Cu(μ-Br)2Cu(NSHC)], and [(NSHC) 2CuBr] have been isolated from in situ generated CuOtBu and N-substituted benzothiazolium halides and characterized by X-ray crystallography. Five structural motifs were observed, viz. MxL y where x:y = 2:2, 4:4, 2:3, 1:2 and 2:4, with Cu⋯Cu separation traversing over a wide range of 2.5626(7) to 3.4725(7) Å distances. A preliminary investigation of the catalytic activity of these compounds indicated that the unusual mononuclear complex 6 [(NSHC) 2CuBr] is an active catalyst for the Huisgen 1,3-dipolar cycloaddition of azide and alkynes while complexes 1-5 and 7 were marginally less active.
AB - A series of novel Cu(I) N,S-heterocyclic carbene (NSHC) complexes [Cu(μ-Br)(NSHC)]2, [Cu(μ-X)(NSHC)]4 (X = Br or I), [(NSHC)2Cu(μ-Br)2Cu(NSHC)], and [(NSHC) 2CuBr] have been isolated from in situ generated CuOtBu and N-substituted benzothiazolium halides and characterized by X-ray crystallography. Five structural motifs were observed, viz. MxL y where x:y = 2:2, 4:4, 2:3, 1:2 and 2:4, with Cu⋯Cu separation traversing over a wide range of 2.5626(7) to 3.4725(7) Å distances. A preliminary investigation of the catalytic activity of these compounds indicated that the unusual mononuclear complex 6 [(NSHC) 2CuBr] is an active catalyst for the Huisgen 1,3-dipolar cycloaddition of azide and alkynes while complexes 1-5 and 7 were marginally less active.
UR - http://www.scopus.com/inward/record.url?scp=84890444137&partnerID=8YFLogxK
U2 - 10.1039/c3dt52059e
DO - 10.1039/c3dt52059e
M3 - Article
AN - SCOPUS:84890444137
VL - 43
SP - 1305
EP - 1312
JO - Dalton Transactions: an international journal of inorganic chemistry
JF - Dalton Transactions: an international journal of inorganic chemistry
SN - 1477-9226
IS - 3
ER -