Abstract
One palladium dichloride adduct of a phosphine-pyridine ligand N-diphenylphosphanyl-2-aminopyridine (L1) [(L1)PdCl2] (1) has been prepared and structurally characterized. Compound 1 can be used as an effective catalyst for the Suzuki-Miyaura cross-coupling reactions of unreactive aryl chlorides with aryl boronic acids, and worked much better than its mono- or bidentate phosphine ligands. The reactions with a wide scope of substrates proceeded to give desired products in good to excellent yields.
Original language | English |
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Pages (from-to) | 3125-3132 |
Number of pages | 8 |
Journal | Tetrahedron |
Volume | 73 |
Issue number | 22 |
DOIs | |
Publication status | Published - 1 Jun 2017 |
Externally published | Yes |