Suzuki-Miyaura cross-coupling reaction of aryl chlorides with aryl boronic acids catalyzed by a palladium dichloride adduct of N-diphenylphosphanyl-2-aminopyridine

Lin Yan Xu, Chun Yu Liu, Shi Yuan Liu, Zhi Gang Ren, David James Young, Jian Ping Lang

Research output: Contribution to journalArticle

Abstract

One palladium dichloride adduct of a phosphine-pyridine ligand N-diphenylphosphanyl-2-aminopyridine (L1) [(L1)PdCl2] (1) has been prepared and structurally characterized. Compound 1 can be used as an effective catalyst for the Suzuki-Miyaura cross-coupling reactions of unreactive aryl chlorides with aryl boronic acids, and worked much better than its mono- or bidentate phosphine ligands. The reactions with a wide scope of substrates proceeded to give desired products in good to excellent yields.

Original languageEnglish
Pages (from-to)3125-3132
Number of pages8
JournalTetrahedron
Volume73
Issue number22
DOIs
Publication statusPublished - 1 Jun 2017
Externally publishedYes

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