Synthesis of two coordination polymer photocatalysts and significant enhancement of their catalytic photodegradation activity by doping with Co2+ Ions

Duan Xiu Li; Zhi Gang Ren; David J. Young; Jian Ping Lang

doi:10.1002/ejic.201500069

Synthesis of two coordination polymer photocatalysts and significant enhancement of their catalytic photodegradation activity by doping with Co²⁺ Ions

Duan Xiu Li, Zhi Gang Ren, David J. Young, Jian Ping Lang

Research output: Contribution to journal › Article

Abstract

The coordination polymers (CPs) [Zn₂(tipm)(1,3-BDC)₂] (1) and [Co₂(tipm)(1,3-BDC)₂]·0.5CH₃CN (2·0.5CH₃CN) were synthesized by the reactions of Zn(NO₃)₂ or Co(NO₃)₂ with tetrakis[4-(1-imidazolyl)phenyl]methane (tipm) and benzene-1,3-dicarboxylic acid (1,3-H₂BDC) under solvothermal conditions. Compounds 1 and 2 are isostructural and possess complicated three-dimensional frameworks with the Schläfli symbol (4·7²)(6²·7³·12)(4·6²·7³). Cobalt ions were incorporated into the Zn-based CP framework 1 during solvothermal crystallization to yield [Zn_(2-2x)Co_2x(tipm)(1,3-BDC)₂]·bH₂O (x = 2.4%, b = 0 for 1a, x = 23%, b = 1 for 2a·H₂O). Doped CPs 1a and 2a·H₂O exhibited greater catalytic photodegradation of the dye rhodamine B (RhB) than the undoped complexes 1 and 2 and many literature examples.

Original language	English
Pages (from-to)	1981-1988
Number of pages	8
Journal	European Journal of Inorganic Chemistry
Volume	2015
Issue number	11
DOIs	https://doi.org/10.1002/ejic.201500069
Publication status	Published - Apr 2015
Externally published	Yes

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@article{28db35c5be664ff3a6e0bb01ee819891,

title = "Synthesis of two coordination polymer photocatalysts and significant enhancement of their catalytic photodegradation activity by doping with Co2+ Ions",

abstract = "The coordination polymers (CPs) [Zn2(tipm)(1,3-BDC)2] (1) and [Co2(tipm)(1,3-BDC)2]·0.5CH3CN (2·0.5CH3CN) were synthesized by the reactions of Zn(NO3)2 or Co(NO3)2 with tetrakis[4-(1-imidazolyl)phenyl]methane (tipm) and benzene-1,3-dicarboxylic acid (1,3-H2BDC) under solvothermal conditions. Compounds 1 and 2 are isostructural and possess complicated three-dimensional frameworks with the Schl{\"a}fli symbol (4·72)(62·73·12)(4·62·73). Cobalt ions were incorporated into the Zn-based CP framework 1 during solvothermal crystallization to yield [Zn(2-2x)Co2x(tipm)(1,3-BDC)2]·bH2O (x = 2.4%, b = 0 for 1a, x = 23%, b = 1 for 2a·H2O). Doped CPs 1a and 2a·H2O exhibited greater catalytic photodegradation of the dye rhodamine B (RhB) than the undoped complexes 1 and 2 and many literature examples.",

keywords = "Carboxylate ligands, Cobalt, Coordination polymers, Doping, N ligands, Photocatalysis, Zinc",

author = "Li, {Duan Xiu} and Ren, {Zhi Gang} and Young, {David J.} and Lang, {Jian Ping}",

year = "2015",

month = apr,

doi = "10.1002/ejic.201500069",

language = "English",

volume = "2015",

pages = "1981--1988",

journal = "European Journal of Inorganic Chemistry",

issn = "1099-0682",

publisher = "Wiley-VCH Verlag",

number = "11",

}

TY - JOUR

T1 - Synthesis of two coordination polymer photocatalysts and significant enhancement of their catalytic photodegradation activity by doping with Co2+ Ions

AU - Li, Duan Xiu

AU - Ren, Zhi Gang

AU - Young, David J.

AU - Lang, Jian Ping

PY - 2015/4

Y1 - 2015/4

N2 - The coordination polymers (CPs) [Zn2(tipm)(1,3-BDC)2] (1) and [Co2(tipm)(1,3-BDC)2]·0.5CH3CN (2·0.5CH3CN) were synthesized by the reactions of Zn(NO3)2 or Co(NO3)2 with tetrakis[4-(1-imidazolyl)phenyl]methane (tipm) and benzene-1,3-dicarboxylic acid (1,3-H2BDC) under solvothermal conditions. Compounds 1 and 2 are isostructural and possess complicated three-dimensional frameworks with the Schläfli symbol (4·72)(62·73·12)(4·62·73). Cobalt ions were incorporated into the Zn-based CP framework 1 during solvothermal crystallization to yield [Zn(2-2x)Co2x(tipm)(1,3-BDC)2]·bH2O (x = 2.4%, b = 0 for 1a, x = 23%, b = 1 for 2a·H2O). Doped CPs 1a and 2a·H2O exhibited greater catalytic photodegradation of the dye rhodamine B (RhB) than the undoped complexes 1 and 2 and many literature examples.

AB - The coordination polymers (CPs) [Zn2(tipm)(1,3-BDC)2] (1) and [Co2(tipm)(1,3-BDC)2]·0.5CH3CN (2·0.5CH3CN) were synthesized by the reactions of Zn(NO3)2 or Co(NO3)2 with tetrakis[4-(1-imidazolyl)phenyl]methane (tipm) and benzene-1,3-dicarboxylic acid (1,3-H2BDC) under solvothermal conditions. Compounds 1 and 2 are isostructural and possess complicated three-dimensional frameworks with the Schläfli symbol (4·72)(62·73·12)(4·62·73). Cobalt ions were incorporated into the Zn-based CP framework 1 during solvothermal crystallization to yield [Zn(2-2x)Co2x(tipm)(1,3-BDC)2]·bH2O (x = 2.4%, b = 0 for 1a, x = 23%, b = 1 for 2a·H2O). Doped CPs 1a and 2a·H2O exhibited greater catalytic photodegradation of the dye rhodamine B (RhB) than the undoped complexes 1 and 2 and many literature examples.

KW - Carboxylate ligands

KW - Cobalt

KW - Coordination polymers

KW - Doping

KW - N ligands

KW - Photocatalysis

KW - Zinc

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U2 - 10.1002/ejic.201500069

DO - 10.1002/ejic.201500069

M3 - Article

VL - 2015

SP - 1981

EP - 1988

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1099-0682

IS - 11

ER -