Abstract
The coordination polymers (CPs) [Zn2(tipm)(1,3-BDC)2] (1) and [Co2(tipm)(1,3-BDC)2]·0.5CH3CN (2·0.5CH3CN) were synthesized by the reactions of Zn(NO3)2 or Co(NO3)2 with tetrakis[4-(1-imidazolyl)phenyl]methane (tipm) and benzene-1,3-dicarboxylic acid (1,3-H2BDC) under solvothermal conditions. Compounds 1 and 2 are isostructural and possess complicated three-dimensional frameworks with the Schläfli symbol (4·72)(62·73·12)(4·62·73). Cobalt ions were incorporated into the Zn-based CP framework 1 during solvothermal crystallization to yield [Zn(2-2x)Co2x(tipm)(1,3-BDC)2]·bH2O (x = 2.4%, b = 0 for 1a, x = 23%, b = 1 for 2a·H2O). Doped CPs 1a and 2a·H2O exhibited greater catalytic photodegradation of the dye rhodamine B (RhB) than the undoped complexes 1 and 2 and many literature examples.
| Original language | English |
|---|---|
| Pages (from-to) | 1981-1988 |
| Number of pages | 8 |
| Journal | European Journal of Inorganic Chemistry |
| Volume | 2015 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Apr 2015 |
| Externally published | Yes |
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Synthesis of two coordination polymer photocatalysts and significant enhancement of their catalytic photodegradation activity by doping with Co2+ Ions. / Li, Duan Xiu; Ren, Zhi Gang; Young, David J.; Lang, Jian Ping.
In: European Journal of Inorganic Chemistry, Vol. 2015, No. 11, 04.2015, p. 1981-1988.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Synthesis of two coordination polymer photocatalysts and significant enhancement of their catalytic photodegradation activity by doping with Co2+ Ions
AU - Li, Duan Xiu
AU - Ren, Zhi Gang
AU - Young, David J.
AU - Lang, Jian Ping
PY - 2015/4
Y1 - 2015/4
N2 - The coordination polymers (CPs) [Zn2(tipm)(1,3-BDC)2] (1) and [Co2(tipm)(1,3-BDC)2]·0.5CH3CN (2·0.5CH3CN) were synthesized by the reactions of Zn(NO3)2 or Co(NO3)2 with tetrakis[4-(1-imidazolyl)phenyl]methane (tipm) and benzene-1,3-dicarboxylic acid (1,3-H2BDC) under solvothermal conditions. Compounds 1 and 2 are isostructural and possess complicated three-dimensional frameworks with the Schläfli symbol (4·72)(62·73·12)(4·62·73). Cobalt ions were incorporated into the Zn-based CP framework 1 during solvothermal crystallization to yield [Zn(2-2x)Co2x(tipm)(1,3-BDC)2]·bH2O (x = 2.4%, b = 0 for 1a, x = 23%, b = 1 for 2a·H2O). Doped CPs 1a and 2a·H2O exhibited greater catalytic photodegradation of the dye rhodamine B (RhB) than the undoped complexes 1 and 2 and many literature examples.
AB - The coordination polymers (CPs) [Zn2(tipm)(1,3-BDC)2] (1) and [Co2(tipm)(1,3-BDC)2]·0.5CH3CN (2·0.5CH3CN) were synthesized by the reactions of Zn(NO3)2 or Co(NO3)2 with tetrakis[4-(1-imidazolyl)phenyl]methane (tipm) and benzene-1,3-dicarboxylic acid (1,3-H2BDC) under solvothermal conditions. Compounds 1 and 2 are isostructural and possess complicated three-dimensional frameworks with the Schläfli symbol (4·72)(62·73·12)(4·62·73). Cobalt ions were incorporated into the Zn-based CP framework 1 during solvothermal crystallization to yield [Zn(2-2x)Co2x(tipm)(1,3-BDC)2]·bH2O (x = 2.4%, b = 0 for 1a, x = 23%, b = 1 for 2a·H2O). Doped CPs 1a and 2a·H2O exhibited greater catalytic photodegradation of the dye rhodamine B (RhB) than the undoped complexes 1 and 2 and many literature examples.
KW - Carboxylate ligands
KW - Cobalt
KW - Coordination polymers
KW - Doping
KW - N ligands
KW - Photocatalysis
KW - Zinc
UR - http://www.scopus.com/inward/record.url?scp=84926665923&partnerID=8YFLogxK
U2 - 10.1002/ejic.201500069
DO - 10.1002/ejic.201500069
M3 - Article
VL - 2015
SP - 1981
EP - 1988
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1099-0682
IS - 11
ER -