The high pressure addition of aldehydes to allylstannanes: A 'Diels-Alder like' transition state

Neil S. Isaacs; Ljiljana Maksimovic; Gavin B. Rintoul; David J. Young

doi:10.1039/C39920001749

The high pressure addition of aldehydes to allylstannanes: A 'Diels-Alder like' transition state

Neil S. Isaacs, Ljiljana Maksimovic, Gavin B. Rintoul, David J. Young

Research output: Contribution to journal › Article

Abstract

The activation volume for the addition of chloral to allyltributylstannane was found to be -33.4 ± 0.6 cm³ mol^-1, which is consistent with a concerted, cyclic transition state.

Original language	English
Pages (from-to)	1749-1750
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1992
Issue number	23
DOIs	https://doi.org/10.1039/C39920001749
Publication status	Published - 1992
Externally published	Yes

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title = "The high pressure addition of aldehydes to allylstannanes: A 'Diels-Alder like' transition state",

abstract = "The activation volume for the addition of chloral to allyltributylstannane was found to be -33.4 ± 0.6 cm3 mol-1, which is consistent with a concerted, cyclic transition state.",

author = "Isaacs, {Neil S.} and Ljiljana Maksimovic and Rintoul, {Gavin B.} and Young, {David J.}",

year = "1992",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T2 - A 'Diels-Alder like' transition state

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AU - Maksimovic, Ljiljana

AU - Rintoul, Gavin B.

AU - Young, David J.

PY - 1992

Y1 - 1992

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AB - The activation volume for the addition of chloral to allyltributylstannane was found to be -33.4 ± 0.6 cm3 mol-1, which is consistent with a concerted, cyclic transition state.

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DO - 10.1039/C39920001749

M3 - Article

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VL - 1992

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

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