The solvent promoted addition of tetraallyltin to aldehydes

A convenient and chemoselective allylation procedure

Teresa M. Cokley, Raymond L. Marshall, Adam McCluskey, David J. Young

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Aldehydes 2a-e react with tetraallyltin (1, 0.25 equiv.) in methanol or orther polar solvent at room temperature (ca 30°C, < 20 h) to provide the corresponding homoallyl alcohols 3a-e in 69-98% yield. No additional catalysis is required.

Original languageEnglish
Pages (from-to)1905-1908
Number of pages4
JournalTetrahedron Letters
Volume37
Issue number11
DOIs
Publication statusPublished - 11 Mar 1996
Externally publishedYes

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Allylation
Catalysis
Aldehydes
Methanol
Alcohols
Temperature

Cite this

Cokley, Teresa M. ; Marshall, Raymond L. ; McCluskey, Adam ; Young, David J. / The solvent promoted addition of tetraallyltin to aldehydes : A convenient and chemoselective allylation procedure. In: Tetrahedron Letters. 1996 ; Vol. 37, No. 11. pp. 1905-1908.
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The solvent promoted addition of tetraallyltin to aldehydes : A convenient and chemoselective allylation procedure. / Cokley, Teresa M.; Marshall, Raymond L.; McCluskey, Adam; Young, David J.

In: Tetrahedron Letters, Vol. 37, No. 11, 11.03.1996, p. 1905-1908.

Research output: Contribution to journalArticleResearchpeer-review

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