Abstract
Nano-sized Co3O4, Fe2O3, Au/Co3O4 and Au/Fe2O3 catalysts were prepared and evaluated for catalytic combustion of lean methane-air mixtures. Characteristics and catalytic activities under dry and wet feed conditions were investigated at gas hourly space velocities up to 100 000 h-1 mimicking the typical flow and conversion requirements of a catalytic system designed to treat a ventilation air methane stream. In order to gain a better understanding of the interaction between H2O and the catalyst surface, temperature-programmed desorption of water over fresh and used samples were studied, and supported by other catalyst characterization techniques such as N2-adsorption desorption, XRD, TEM, SEM and XPS analyses. The activity measurements of the catalysts studied identify Co3O4 as the most active material. Co-precipitating gold particles with cobalt oxide or iron oxide do not enhance the activity of the catalyst, which is most likely due to blocking the active site of support by the gold particle. The presence of strong hydroxyl bonds on the catalyst surface is substantiated by TPD and XPS analyses, and is suggested to be responsible for the rapid deactivation of Fe2O3 and Au/Fe2O3 catalysts.
| Original language | English |
|---|---|
| Pages (from-to) | 276-283 |
| Number of pages | 8 |
| Journal | Catalysis Today |
| Volume | 258 |
| Issue number | Part 2 |
| Early online date | 2 Jan 2015 |
| DOIs | |
| Publication status | Published - 1 Dec 2015 |
| Externally published | Yes |
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The stability of Co3O4, Fe2O3, Au/Co3O4 and Au/Fe2O3 catalysts in the catalytic combustion of lean methane mixtures in the presence of water. / Setiawan, Adi; Kennedy, Eric M.; Dlugogorski, Bogdan Z.; Adesina, Adesoji A.; Stockenhuber, Michael.
In: Catalysis Today, Vol. 258, No. Part 2, 01.12.2015, p. 276-283.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - The stability of Co3O4, Fe2O3, Au/Co3O4 and Au/Fe2O3 catalysts in the catalytic combustion of lean methane mixtures in the presence of water
AU - Setiawan, Adi
AU - Kennedy, Eric M.
AU - Dlugogorski, Bogdan Z.
AU - Adesina, Adesoji A.
AU - Stockenhuber, Michael
PY - 2015/12/1
Y1 - 2015/12/1
N2 - Nano-sized Co3O4, Fe2O3, Au/Co3O4 and Au/Fe2O3 catalysts were prepared and evaluated for catalytic combustion of lean methane-air mixtures. Characteristics and catalytic activities under dry and wet feed conditions were investigated at gas hourly space velocities up to 100 000 h-1 mimicking the typical flow and conversion requirements of a catalytic system designed to treat a ventilation air methane stream. In order to gain a better understanding of the interaction between H2O and the catalyst surface, temperature-programmed desorption of water over fresh and used samples were studied, and supported by other catalyst characterization techniques such as N2-adsorption desorption, XRD, TEM, SEM and XPS analyses. The activity measurements of the catalysts studied identify Co3O4 as the most active material. Co-precipitating gold particles with cobalt oxide or iron oxide do not enhance the activity of the catalyst, which is most likely due to blocking the active site of support by the gold particle. The presence of strong hydroxyl bonds on the catalyst surface is substantiated by TPD and XPS analyses, and is suggested to be responsible for the rapid deactivation of Fe2O3 and Au/Fe2O3 catalysts.
AB - Nano-sized Co3O4, Fe2O3, Au/Co3O4 and Au/Fe2O3 catalysts were prepared and evaluated for catalytic combustion of lean methane-air mixtures. Characteristics and catalytic activities under dry and wet feed conditions were investigated at gas hourly space velocities up to 100 000 h-1 mimicking the typical flow and conversion requirements of a catalytic system designed to treat a ventilation air methane stream. In order to gain a better understanding of the interaction between H2O and the catalyst surface, temperature-programmed desorption of water over fresh and used samples were studied, and supported by other catalyst characterization techniques such as N2-adsorption desorption, XRD, TEM, SEM and XPS analyses. The activity measurements of the catalysts studied identify Co3O4 as the most active material. Co-precipitating gold particles with cobalt oxide or iron oxide do not enhance the activity of the catalyst, which is most likely due to blocking the active site of support by the gold particle. The presence of strong hydroxyl bonds on the catalyst surface is substantiated by TPD and XPS analyses, and is suggested to be responsible for the rapid deactivation of Fe2O3 and Au/Fe2O3 catalysts.
KW - Catalytic combustion
KW - Cobalt oxide
KW - Gold
KW - Iron oxide
KW - Methane
KW - Water inhibition
UR - http://www.scopus.com/inward/record.url?scp=84935421013&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2014.11.031
DO - 10.1016/j.cattod.2014.11.031
M3 - Article
VL - 258
SP - 276
EP - 283
JO - Catalysis Today
JF - Catalysis Today
SN - 0920-5861
IS - Part 2
ER -