TY - JOUR
T1 - The stereochemistry of high pressure aldehyde addition to allylstannanes
AU - Isaacs, Neil S.
AU - Marshall, Raymond L.
AU - Young, David J.
PY - 1992/5/19
Y1 - 1992/5/19
N2 - The high pressure (9 kbar, 30°C) mediated addition of benzaldehyde to allylstannane (1) occurs stereospecifically with syn approach of the electrophile. At 60°C, the reaction is less selective, probably due to some isomerization of cis (1) to trans (1). At both temperatures good erythro diastereoselectivity is observed.
AB - The high pressure (9 kbar, 30°C) mediated addition of benzaldehyde to allylstannane (1) occurs stereospecifically with syn approach of the electrophile. At 60°C, the reaction is less selective, probably due to some isomerization of cis (1) to trans (1). At both temperatures good erythro diastereoselectivity is observed.
UR - http://www.scopus.com/inward/record.url?scp=0026683555&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(00)79589-X
DO - 10.1016/S0040-4039(00)79589-X
M3 - Article
AN - SCOPUS:0026683555
VL - 33
SP - 3023
EP - 3024
JO - Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry
JF - Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry
SN - 0040-4039
IS - 21
ER -