The stereochemistry of high pressure aldehyde addition to allylstannanes

Neil S. Isaacs, Raymond L. Marshall, David J. Young

Research output: Contribution to journalArticle

Abstract

The high pressure (9 kbar, 30°C) mediated addition of benzaldehyde to allylstannane (1) occurs stereospecifically with syn approach of the electrophile. At 60°C, the reaction is less selective, probably due to some isomerization of cis (1) to trans (1). At both temperatures good erythro diastereoselectivity is observed.

Original languageEnglish
Pages (from-to)3023-3024
Number of pages2
JournalTetrahedron Letters
Volume33
Issue number21
DOIs
Publication statusPublished - 19 May 1992
Externally publishedYes

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