Abstract
The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
| Original language | English |
|---|---|
| Pages (from-to) | 1381-1382 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Volume | 1994 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 1 Dec 1994 |
| Externally published | Yes |
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The thermal decomposition of allylic sulfinic acids : A study of a retro-ene transition state. / Hiscock, Steven D.; Isaacs, Neil S.; King, Malcolm D.; Young, David J.
In: Journal of the Chemical Society, Chemical Communications, Vol. 1994, No. 11, 01.12.1994, p. 1381-1382.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - The thermal decomposition of allylic sulfinic acids
T2 - A study of a retro-ene transition state
AU - Hiscock, Steven D.
AU - Isaacs, Neil S.
AU - King, Malcolm D.
AU - Young, David J.
PY - 1994/12/1
Y1 - 1994/12/1
N2 - The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
AB - The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
UR - http://www.scopus.com/inward/record.url?scp=37049081590&partnerID=8YFLogxK
U2 - 10.1039/C39940001381
DO - 10.1039/C39940001381
M3 - Article
VL - 1994
SP - 1381
EP - 1382
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 11
ER -