The thermal decomposition of allylic sulfinic acids: A study of a retro-ene transition state

Steven D. Hiscock; Neil S. Isaacs; Malcolm D. King; David J. Young

doi:10.1039/C39940001381

The thermal decomposition of allylic sulfinic acids: A study of a retro-ene transition state

Steven D. Hiscock, Neil S. Isaacs, Malcolm D. King, David J. Young

Research output: Contribution to journal › Article

Abstract

The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.

Original language	English
Pages (from-to)	1381-1382
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1994
Issue number	11
DOIs	https://doi.org/10.1039/C39940001381
Publication status	Published - 1 Dec 1994
Externally published	Yes

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Hiscock, S. D., Isaacs, N. S., King, M. D., & Young, D. J. (1994). The thermal decomposition of allylic sulfinic acids: A study of a retro-ene transition state. Journal of the Chemical Society, Chemical Communications, 1994(11), 1381-1382. https://doi.org/10.1039/C39940001381

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abstract = "The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.",

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