The thermal decomposition of allylic sulfinic acids

A study of a retro-ene transition state

Steven D. Hiscock, Neil S. Isaacs, Malcolm D. King, David J. Young

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.

Original languageEnglish
Pages (from-to)1381-1382
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume1994
Issue number11
DOIs
Publication statusPublished - 1 Dec 1994
Externally publishedYes

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Sulfinic Acids
Deuterium
Isotopes
Hot Temperature
Acids

Cite this

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abstract = "The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.",
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The thermal decomposition of allylic sulfinic acids : A study of a retro-ene transition state. / Hiscock, Steven D.; Isaacs, Neil S.; King, Malcolm D.; Young, David J.

In: Journal of the Chemical Society, Chemical Communications, Vol. 1994, No. 11, 01.12.1994, p. 1381-1382.

Research output: Contribution to journalArticleResearchpeer-review

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T2 - A study of a retro-ene transition state

AU - Hiscock, Steven D.

AU - Isaacs, Neil S.

AU - King, Malcolm D.

AU - Young, David J.

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AB - The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.

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