The thermal desulfination of allylic sulfonyl halides

Malcolm D. King; Rodney E. Sue; Rodney H. White; David J. Young

doi:10.1016/S0040-4039(97)00911-8

The thermal desulfination of allylic sulfonyl halides

Malcolm D. King, Rodney E. Sue, Rodney H. White, David J. Young

Research output: Contribution to journal › Article

Abstract

Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with γ-syn bromine migration.

Original language	English
Pages (from-to)	4493-4496
Number of pages	4
Journal	Tetrahedron Letters
Volume	38
Issue number	25
DOIs	https://doi.org/10.1016/S0040-4039(97)00911-8
Publication status	Published - 23 Jun 1997
Externally published	Yes

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10.1016/S0040-4039(97)00911-8

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King, M. D., Sue, R. E., White, R. H., & Young, D. J. (1997). The thermal desulfination of allylic sulfonyl halides. Tetrahedron Letters, 38(25), 4493-4496. https://doi.org/10.1016/S0040-4039(97)00911-8

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