Thermal decomposition of allylic sulfinic acids

Confirmation of a retro-ene mechanism

Malcolm D. King, Rodney E. Sue, Rodney H. White, David J. Young

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

Original languageEnglish
Pages (from-to)1797-1798
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume1993
Issue number24
DOIs
Publication statusPublished - 1993
Externally publishedYes

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title = "Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism",
abstract = "The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.",
author = "King, {Malcolm D.} and Sue, {Rodney E.} and White, {Rodney H.} and Young, {David J.}",
year = "1993",
doi = "10.1039/C39930001797",
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pages = "1797--1798",
journal = "Journal of the Chemical Society, Chemical Communications",
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Thermal decomposition of allylic sulfinic acids : Confirmation of a retro-ene mechanism. / King, Malcolm D.; Sue, Rodney E.; White, Rodney H.; Young, David J.

In: Journal of the Chemical Society, Chemical Communications, Vol. 1993, No. 24, 1993, p. 1797-1798.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Thermal decomposition of allylic sulfinic acids

T2 - Confirmation of a retro-ene mechanism

AU - King, Malcolm D.

AU - Sue, Rodney E.

AU - White, Rodney H.

AU - Young, David J.

PY - 1993

Y1 - 1993

N2 - The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

AB - The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

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U2 - 10.1039/C39930001797

DO - 10.1039/C39930001797

M3 - Article

VL - 1993

SP - 1797

EP - 1798

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

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