Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism

Malcolm D. King; Rodney E. Sue; Rodney H. White; David J. Young

doi:10.1039/C39930001797

Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism

Malcolm D. King, Rodney E. Sue, Rodney H. White, David J. Young

Research output: Contribution to journal › Article

Abstract

The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

Original language	English
Pages (from-to)	1797-1798
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1993
Issue number	24
DOIs	https://doi.org/10.1039/C39930001797
Publication status	Published - 1993
Externally published	Yes

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King, M. D., Sue, R. E., White, R. H., & Young, D. J. (1993). Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism. Journal of the Chemical Society, Chemical Communications, 1993(24), 1797-1798. https://doi.org/10.1039/C39930001797

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abstract = "The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.",

author = "King, {Malcolm D.} and Sue, {Rodney E.} and White, {Rodney H.} and Young, {David J.}",

year = "1993",

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AU - King, Malcolm D.

AU - Sue, Rodney E.

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AU - Young, David J.

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AB - The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

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DO - 10.1039/C39930001797

M3 - Article

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JO - Journal of the Chemical Society, Chemical Communications

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10.1039/C39930001797

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