Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism

Malcolm D. King; Rodney E. Sue; Rodney H. White; David J. Young

doi:10.1039/C39930001797

Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism

Malcolm D. King, Rodney E. Sue, Rodney H. White, David J. Young

Research output: Contribution to journal › Article › peer-review

Abstract

The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

Original language	English
Pages (from-to)	1797-1798
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1993
Issue number	24
DOIs	https://doi.org/10.1039/C39930001797
Publication status	Published - 1993
Externally published	Yes

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title = "Thermal decomposition of allylic sulfinic acids: Confirmation of a retro-ene mechanism",

abstract = "The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.",

author = "King, {Malcolm D.} and Sue, {Rodney E.} and White, {Rodney H.} and Young, {David J.}",

year = "1993",

doi = "10.1039/C39930001797",

language = "English",

volume = "1993",

pages = "1797--1798",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Thermal decomposition of allylic sulfinic acids

T2 - Confirmation of a retro-ene mechanism

AU - King, Malcolm D.

AU - Sue, Rodney E.

AU - White, Rodney H.

AU - Young, David J.

PY - 1993

Y1 - 1993

N2 - The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

AB - The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.

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DO - 10.1039/C39930001797

M3 - Article

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VL - 1993

SP - 1797

EP - 1798

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

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