trans-[Ni(pdm)2]2+ (pdm = 2-pyridinemethanol) as a reliable synthon for isoreticular metal–organic frameworks of linear dicarboxylates

Pin Pin Ma; Zhi Min Hao; Pan Wang; Wen Hua Zhang; David J. Young

doi:10.1016/j.jssc.2022.123721

trans-[Ni(pdm)₂]²⁺ (pdm = 2-pyridinemethanol) as a reliable synthon for isoreticular metal–organic frameworks of linear dicarboxylates

Pin Pin Ma, Zhi Min Hao, Pan Wang, Wen Hua Zhang, David J. Young

CDU College of Engineering, IT and Environment

Research output: Contribution to journal › Article › peer-review

Abstract

trans-[Ni(pdm)₂]²⁺ (pdm = 2-pyridinemethanol) proved to be a reliable synthon for the construction of isoreticular metal–organic frameworks (MOFs) of linear dicarboxylates, as exemplified by three one-dimensional (1D) MOFs [Ni(pdm)₂(BDC)]_n (1), [Ni(pdm)₂(NDA)]_n∙nDMF (2), and [Ni(pdm)₂(ADC)]_n (3) (H₂BDC = 1,4-benzenedicarboxylic acid; H₂NDA = naphthalene-2,6-dicarboxylic acid; H₂ADC = 9,10-anthracenedicarboxylic acid; DMF = N,N-dimethylformamide) which shared identical connectivity. A dinuclear cluster [Ni₂(pdm)₄(HBTC)₂]∙2DMF (4) was formed from tricarboxylate ligand BTC (H₃BTC = benzene-1,3,5-tricarboxylic acid) with the two pdm ligands aligned cis to one other. Single-crystal structure analysis indicated that the 1D chains of 1 − 3 were stacked at different angles in the solid state, resulting in different crystal packing patterns, including a pseudo Kagome-like cross-section for 1, 1D channels for 2 with DMF guest species, and a non-porous structure for 3.

Original language	English
Article number	123721
Pages (from-to)	1-9
Number of pages	9
Journal	Journal of Solid State Chemistry
Volume	317
DOIs	https://doi.org/10.1016/j.jssc.2022.123721
Publication status	Published - Jan 2023

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@article{5b936c83a3014a52b8f3409a26076f9b,

title = "trans-[Ni(pdm)2]2+ (pdm = 2-pyridinemethanol) as a reliable synthon for isoreticular metal–organic frameworks of linear dicarboxylates",

abstract = "trans-[Ni(pdm)2]2+ (pdm = 2-pyridinemethanol) proved to be a reliable synthon for the construction of isoreticular metal–organic frameworks (MOFs) of linear dicarboxylates, as exemplified by three one-dimensional (1D) MOFs [Ni(pdm)2(BDC)]n (1), [Ni(pdm)2(NDA)]n∙nDMF (2), and [Ni(pdm)2(ADC)]n (3) (H2BDC = 1,4-benzenedicarboxylic acid; H2NDA = naphthalene-2,6-dicarboxylic acid; H2ADC = 9,10-anthracenedicarboxylic acid; DMF = N,N-dimethylformamide) which shared identical connectivity. A dinuclear cluster [Ni2(pdm)4(HBTC)2]∙2DMF (4) was formed from tricarboxylate ligand BTC (H3BTC = benzene-1,3,5-tricarboxylic acid) with the two pdm ligands aligned cis to one other. Single-crystal structure analysis indicated that the 1D chains of 1 − 3 were stacked at different angles in the solid state, resulting in different crystal packing patterns, including a pseudo Kagome-like cross-section for 1, 1D channels for 2 with DMF guest species, and a non-porous structure for 3.",

keywords = "2-pyridinemethanol, Crystal structure, Hydrogen bonding, Kagome topology, Metal–organic frameworks",

author = "Ma, {Pin Pin} and Hao, {Zhi Min} and Pan Wang and Zhang, {Wen Hua} and Young, {David J.}",

note = "Funding Information: The authors thank the National Natural Science Foundation of China (Grant No. 21871203 ) for financial support. Publisher Copyright: {\textcopyright} 2022 Elsevier Inc.",

year = "2023",

month = jan,

doi = "10.1016/j.jssc.2022.123721",

language = "English",

volume = "317",

pages = "1--9",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - trans-[Ni(pdm)2]2+ (pdm = 2-pyridinemethanol) as a reliable synthon for isoreticular metal–organic frameworks of linear dicarboxylates

AU - Ma, Pin Pin

AU - Hao, Zhi Min

AU - Wang, Pan

AU - Zhang, Wen Hua

AU - Young, David J.

PY - 2023/1

Y1 - 2023/1

N2 - trans-[Ni(pdm)2]2+ (pdm = 2-pyridinemethanol) proved to be a reliable synthon for the construction of isoreticular metal–organic frameworks (MOFs) of linear dicarboxylates, as exemplified by three one-dimensional (1D) MOFs [Ni(pdm)2(BDC)]n (1), [Ni(pdm)2(NDA)]n∙nDMF (2), and [Ni(pdm)2(ADC)]n (3) (H2BDC = 1,4-benzenedicarboxylic acid; H2NDA = naphthalene-2,6-dicarboxylic acid; H2ADC = 9,10-anthracenedicarboxylic acid; DMF = N,N-dimethylformamide) which shared identical connectivity. A dinuclear cluster [Ni2(pdm)4(HBTC)2]∙2DMF (4) was formed from tricarboxylate ligand BTC (H3BTC = benzene-1,3,5-tricarboxylic acid) with the two pdm ligands aligned cis to one other. Single-crystal structure analysis indicated that the 1D chains of 1 − 3 were stacked at different angles in the solid state, resulting in different crystal packing patterns, including a pseudo Kagome-like cross-section for 1, 1D channels for 2 with DMF guest species, and a non-porous structure for 3.

AB - trans-[Ni(pdm)2]2+ (pdm = 2-pyridinemethanol) proved to be a reliable synthon for the construction of isoreticular metal–organic frameworks (MOFs) of linear dicarboxylates, as exemplified by three one-dimensional (1D) MOFs [Ni(pdm)2(BDC)]n (1), [Ni(pdm)2(NDA)]n∙nDMF (2), and [Ni(pdm)2(ADC)]n (3) (H2BDC = 1,4-benzenedicarboxylic acid; H2NDA = naphthalene-2,6-dicarboxylic acid; H2ADC = 9,10-anthracenedicarboxylic acid; DMF = N,N-dimethylformamide) which shared identical connectivity. A dinuclear cluster [Ni2(pdm)4(HBTC)2]∙2DMF (4) was formed from tricarboxylate ligand BTC (H3BTC = benzene-1,3,5-tricarboxylic acid) with the two pdm ligands aligned cis to one other. Single-crystal structure analysis indicated that the 1D chains of 1 − 3 were stacked at different angles in the solid state, resulting in different crystal packing patterns, including a pseudo Kagome-like cross-section for 1, 1D channels for 2 with DMF guest species, and a non-porous structure for 3.

KW - 2-pyridinemethanol

KW - Crystal structure

KW - Hydrogen bonding

KW - Kagome topology

KW - Metal–organic frameworks

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U2 - 10.1016/j.jssc.2022.123721

DO - 10.1016/j.jssc.2022.123721

M3 - Article

AN - SCOPUS:85142145494

VL - 317

SP - 1

EP - 9

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

M1 - 123721

ER -

trans-[Ni(pdm)₂]²⁺ (pdm = 2-pyridinemethanol) as a reliable synthon for isoreticular metal–organic frameworks of linear dicarboxylates

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