Tuning the configuration of the flexible metal-alkene-framework affords pure cycloisomers in solid state photodimerization

Yong Wang; Meng Fan Wang; David James Young; Hua Zhu; Fei Long Hu; Yan Mi; Zhen Qin; Shu Li Chen; Jian Ping Lang

doi:10.1039/d0cc06939f

Tuning the configuration of the flexible metal-alkene-framework affords pure cycloisomers in solid state photodimerization

Yong Wang, Meng Fan Wang, David James Young, Hua Zhu, Fei Long Hu, Yan Mi, Zhen Qin, Shu Li Chen, Jian Ping Lang

Research output: Contribution to journal › Article › peer-review

Abstract

The photochemical [2+2] cycloaddition of 3,5-bis-(2-(pyridin-4-yl)vinyl)pyridine (bpvp) in the flexible Cd-based metal-alkene frameworks produced different isomeric photoproducts depending on the auxiliary and guest molecules. The bulkiness of the guest molecules influenced the conformation of the ligand, and thus the outcome of the cycloaddition reaction.

Original language	English
Pages (from-to)	1129-1132
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	9
DOIs	https://doi.org/10.1039/d0cc06939f
Publication status	Published - 28 Jan 2021

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abstract = "The photochemical [2+2] cycloaddition of 3,5-bis-(2-(pyridin-4-yl)vinyl)pyridine (bpvp) in the flexible Cd-based metal-alkene frameworks produced different isomeric photoproducts depending on the auxiliary and guest molecules. The bulkiness of the guest molecules influenced the conformation of the ligand, and thus the outcome of the cycloaddition reaction.",

author = "Yong Wang and Wang, {Meng Fan} and Young, {David James} and Hua Zhu and Hu, {Fei Long} and Yan Mi and Zhen Qin and Chen, {Shu Li} and Lang, {Jian Ping}",

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T1 - Tuning the configuration of the flexible metal-alkene-framework affords pure cycloisomers in solid state photodimerization

AU - Wang, Yong

AU - Wang, Meng Fan

AU - Young, David James

AU - Zhu, Hua

AU - Hu, Fei Long

AU - Mi, Yan

AU - Qin, Zhen

AU - Chen, Shu Li

AU - Lang, Jian Ping

PY - 2021/1/28

Y1 - 2021/1/28

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AB - The photochemical [2+2] cycloaddition of 3,5-bis-(2-(pyridin-4-yl)vinyl)pyridine (bpvp) in the flexible Cd-based metal-alkene frameworks produced different isomeric photoproducts depending on the auxiliary and guest molecules. The bulkiness of the guest molecules influenced the conformation of the ligand, and thus the outcome of the cycloaddition reaction.

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U2 - 10.1039/d0cc06939f

DO - 10.1039/d0cc06939f

M3 - Article

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AN - SCOPUS:85100258164

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VL - 57

SP - 1129

EP - 1132

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Tuning the configuration of the flexible metal-alkene-framework affords pure cycloisomers in solid state photodimerization

Abstract

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