Versatile palladium(II)-catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand

Jin Jiao Ning, Jian Feng Wang, Zhi Gang Ren, David James Young, Jian Ping Lang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Suzuki-Miyaura coupling reactions of arylboronic acids with aryl bromides were mediated by PdCl2 and bdppmapy (N,N-bis-(diphenylphosphanylmethyl)-2-aminopyridine) that both stabilizes and solubilizes the catalyst in predominantly ethanol as a solvent. Excellent yields for a wide variety of substrates were obtained under relatively mild conditions in this 'green' solvent.

Original languageEnglish
Pages (from-to)4000-4006
Number of pages7
JournalTetrahedron
Volume71
Issue number23
DOIs
Publication statusPublished - 10 Jun 2015
Externally publishedYes

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Palladium
Ethanol
Ligands
Bromides
Catalysts
Acids
Substrates
palladium chloride
alpha-aminopyridine

Cite this

Ning, Jin Jiao ; Wang, Jian Feng ; Ren, Zhi Gang ; Young, David James ; Lang, Jian Ping. / Versatile palladium(II)-catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand. In: Tetrahedron. 2015 ; Vol. 71, No. 23. pp. 4000-4006.
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Versatile palladium(II)-catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand. / Ning, Jin Jiao; Wang, Jian Feng; Ren, Zhi Gang; Young, David James; Lang, Jian Ping.

In: Tetrahedron, Vol. 71, No. 23, 10.06.2015, p. 4000-4006.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Wang, Jian Feng

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AU - Lang, Jian Ping

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